无机材料学报Issue(3)：305-310,6.DOI:10.15541/jim20140391
核壳结构氧化镍/碳微球的制备及葡萄糖传感性能
Preparation and Glucose Sensing Property of Core-shelled Nikel Oxide/Carbon Microspheres
摘要
Abstract
By using carbon spheres as a template, precursor Ni(OH)2/C were prepared by a hydrothermal synthesis technology with the reaction of hexahydrate nickel chloride and urea. And then the precursor was calcinated in pure nitrogen to obtain core-shelled NiO/C microspheres. Scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray energy dispersive (EDX), and the thermo gravimetric analyzer (TGA) were used to characterize morphology and structure of the samples. Results show that the NiO/C microspheres have core-shell structure with diameter around 1.4μm, carbon sphere as the core, and cubic NiO nanoplates with thickness of 50 nm as the shell. Electrochemical behavior and sensing property of core-shelled NiO/C microspheres were studied via cyclic voltammetry and amperometric method. The results displayed that glucose sensitivity of the NiO/C is 31.37mA/(mmol·L-1·cm2)better than that of NiO, among the linear range of 2–1279μmol/L with detecting limit at 2μmol/L. Furthermore, the core-shelled NiO/C microspheres exhibit good stability and anti-interference ability.关键词
核壳结构/NiO/C花状微球/葡萄糖/电化学传感Key words
core-shelled structure/NiO/C flower-like microsphere/glucose/electrochemical sensor分类
化学化工引用本文复制引用
崔振珍,殷好勇,赵红挺,聂秋林..核壳结构氧化镍/碳微球的制备及葡萄糖传感性能[J].无机材料学报,2015,(3):305-310,6.基金项目
国家自然科学基金(41271249) National Natural Science Foundation of China (41271249) （41271249）
