无机材料学报Issue(7):763-768,6.DOI:10.15541/jim20140686
石墨烯包覆玻璃纤维复合材料的制备及其电学性能研究
Preparation and Electrical Properties of Graphene Coated Glass Fiber Composites
摘要
Abstract
The graphene coated glass fiber composites were obtained from the electrostatic adsorption of graphene oxide on bovine serum albumin (BSA) modified the glass fibers, and the subsequent reduction of graphene oxide coated glass fibers by hydroiodic acid at low temperature of 40℃. The phase structure and functional groups of gra-phene oxide were studied by XRD and FT-IR, respectively. SEM images showed that the graphene wrapped effect was improved with pH decreasing, when pH of graphene oxide dispersion was less than 6. Zeta potential of graphene oxide and BSA molecule were tested by Particle size/Zeta potential instrument, which showed that the isoelectric points of graphene oxide and BSA were smaller than 3 and 5.3, respectively. Conductivity of graphene wrapped glass fiber composites reached 4.5 S/m, and conductive glass fibers maintained original conductivity after different levels of bending. Moreover, due to the reduction of graphene, the conductivity increased slightly after the heat-treatment above 100℃. These results prove that the conductive glass fibers can be used at high temperature.关键词
玻璃纤维/牛血清白蛋白/石墨烯Key words
glass fiber/bovine serum albumin/graphene分类
化学化工引用本文复制引用
刘国强,石福志,李耀刚,张青红,王宏志..石墨烯包覆玻璃纤维复合材料的制备及其电学性能研究[J].无机材料学报,2015,(7):763-768,6.基金项目
高等学校学科创新引智计划(111-2-04) (111-2-04)
高等学校博士学科点专项科研基金(20110075130001) (20110075130001)
教育部创新团队发展计划(IRT1221) (IRT1221)
上海市科委项目(12nm0503900,13JC1400200) (12nm0503900,13JC1400200)
中国博士后科学基金(2014M561468) Program of Introducing Talents of Discipline to Universities(111-2-04) (2014M561468)
Specialized Research Fund for the Doctoral Program of Higher Education(20110075130001) (20110075130001)
Innovative Research Team in University(IRT1221) (IRT1221)
Sci-ence and Technology Commission of Shanghai Municipality(12nm0503900,13JC1400200) (12nm0503900,13JC1400200)
China Postdoctoral Science Foundation Funded Project(2014M561468) (2014M561468)