物理化学学报Issue(8)：1393-1407,15.DOI:10.3866/PKU.WHXB201406171
碱性固体燃料电池碱性聚合物电解质膜的最新研究进展
Recent Research Progress in Alkaline Polymer Electrolyte Membranes for Alkaline Solid Fuel Cells
摘要
Abstract
Alkaline polymer electrolyte membrane fuel cell (APEMFC) has received much recent attention, primarily motivated by their fast dynamics and independence on expensive Pt-based electrocatalysts. As one of vital components of APEMFC, the alkaline polymer membrane directly influences their performance and cost. However, to date, no alkaline membrane has provided a satisfactory benchmark for use in APEMFC. Therefore, intensive efforts have been made to pursue desirable polymer membrane materials. In this article, the research progress over the last 3 years on state-of-the-art alkaline polymer electrolyte membranes for APEMFC is reviewed, including various synthesis strategies, structure-property relationships, water management, and ex situ and in situ stability tests. More specifically, some new metal-cation-based anion exchange membranes, such as ruthenium-complex-based and crown-ether-based anion exchange membranes, are commented on for the first time. Furthermore, future development prospects are also predicted.关键词
碱性固体燃料电池/碱性聚合物电解质膜/阴离子交换膜/复合膜/非铂催化剂Key words
Alkaline solid fuel cell/Alkaline polymer electrolyte membrane/Anion exchange membrane/Composite membrane/Non-Pt catalyst分类
化学化工引用本文复制引用
侯宏英..碱性固体燃料电池碱性聚合物电解质膜的最新研究进展[J].物理化学学报,2014,(8):1393-1407,15.基金项目
The project was supported by the National Natural Science Foundation of China (51363011), the 46th Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education, China (6488-20130039), Program of High-level Introduced Talent of Yunnan Province in 2012, China (10978125), and Yunnan Project of Training Talent, China (1418425) and Project of Key Discipline, China (14078232).国家自然科学基金(51363011),第46批教育部留学归国基金(6488-20130039),云南省2012年高层次引进人才经费(10978125),云南省人才培养基金(1418425)和重点学科项目(14078232)资助项目 （51363011）
