物理化学学报Issue(4)：685-692,8.DOI:10.3866/PKU.WHXB201502022
多巴胺改性聚吡咯衍生掺氮多孔碳材料的制备及其超电容性能
Nitrogen-Doped Porous Carbon Derived from Dopamine-Modified Polypyrrole and Its Electrochemical Capacitive Behavior
摘要
Abstract
Carbonization of a nitrogen-containing polymer under inert atmosphere has been used to obtain nitrogen-enriched carbon materials. Herein, we synthesized dopamine-modified polypyrrole (PDA-PPy) via chemical polymerization, which was then carbonized under nitrogen atmosphere to produce nitrogen-doped porous carbon materials (NPC). The structure and morphology of the NPC were investigated by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). By regulating the molar ratio of pyrrole monomer to dopamine, the morphology of PDA-PPy and the capacitive performance of NPC could be control ed. At a current density of 0.5 A∙g-1, the specific capacitance of NPC-0.5 (the molar ratio of dopamine to pyrrole monomer is 0.5) is ca 210 F∙g-1. Even at a current density of 10 A∙g-1, the specific capacitance of NPC-0.5 is up to 134 F∙g-1 and the retention rate is 63.8%.关键词
吡咯/多巴胺/多孔碳/氮掺杂/超级电容器Key words
Pyrrole/Dopamine/Porous carbon/Nitrogen-doping/Supercapacitor分类
化学化工引用本文复制引用
杨硕,徐桂银,韩金鹏,邴欢,窦辉,张校刚..多巴胺改性聚吡咯衍生掺氮多孔碳材料的制备及其超电容性能[J].物理化学学报,2015,(4):685-692,8.基金项目
The project was supported by the National Key Basic Research Program of China (973)(2014CB239701), National Natural Science Foundation of China (21103091,21173120,51372116), and Natural Science Foundation of Jiangsu Province, China (BK2011030).国家重点基础研究发展规划(973)(2014CB239701),国家自然科学基金(21103091,21173120,51372116)以及江苏省自然科学基金(BK2011030)资助项目 （973）
