物理学报Issue(3)：85-94,10.DOI:10.7498/aps.64.038405
有机无机杂化固态太阳能电池的研究进展∗
Recent progress in research on solid organic-inorganic hybrid solar cells
摘要
Abstract
Recently solid-state organic-inorganic hybrid solar cells based on perovskite structured materials have evidenced a great breakthrough due to their perfect light absorption and charge transfer optoelectronic properties. The power conversion efficiencies have exceeded 20.1% during the last 5 years, since the first report on perovskite solar cells with an efficiency of 3.8% in 2009. Remarkably, perovskite solar cells with a planar-heterojunction structure have achieved an efficiency of 19.3%, and the perovskite solar cells with conventional mesoporous structure have achieved a certified efficiency above 16.7%. This review article first introduces the development of the third generation of solar cells from dye-sensitized solar cells to the perovskite solar cells, and then focuses on the optical and physical properties of the perovskite materials and their application in solid-state solar cells. We discuss the performance characteristics and advantages of the perovskite solar cells having mesoporous, planar heterojunction, flexibility, and hole-conductor-free structure respectively, and the charge collection layer which is applied in perovskite solar cells, such as semiconductor oxide (TiO2, Al2O3, ZnO and NiO) and PEDOT:PSS, etc. More over this review article introduces the charge transport materials, including P3HT, spiro-OMeTAD, PTAA, and PCBM, as well as different photoabsorption material, such as CH3NH3PbI3, CH3NH3PbBr3 and CH3NH3PbI3−xClx, etc. aiming to analyze their performance characteristic in the perovskite solar cells with different configurations; and the main factor related to the performance. Finally, this review elaborates the perspective and understanding of the perovskite solar cells and points out the critical point and expectation for improving the performance of perovskite solar cells further.关键词
钙钛矿/太阳能电池/光电转换效率Key words
perovskite/solar cells/power conversion efficiency引用本文复制引用
袁怀亮,李俊鹏,王鸣魁..有机无机杂化固态太阳能电池的研究进展∗[J].物理学报,2015,(3):85-94,10.基金项目
国家重点基础研究发展计划(批准号:2011CBA00703)、国家自然科学基金(批准号:201173091)、云南省财政厅、工信委2014年可再生能源发展专项和教育部新世纪优秀人才(批准号：NCET-10-0416)资助的课题.* Project supported by the State Key Development Program for Basic Research of China (Grant No.2011CBA00703), the National Natural Science Foundation of China (Grant No.201173091), the 2014 Renewable Energy Development Project of Yunnan Provincial Department of Finance and Industry&Information Technology Commission, and the CME with the Program of New Century Excellent Talents in University of China (Grant No. NCET-10-0416) （批准号:2011CBA00703）
