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丙烯酸酯改性水性聚氨酯乳液的合成及性能

李庆 樊增禄 蔡信彬 张龙 赵晓剑

西安工程大学学报Issue(2):140-145,6.
西安工程大学学报Issue(2):140-145,6.DOI:10.13338/j.issn.1674-649x.2015.02.002

丙烯酸酯改性水性聚氨酯乳液的合成及性能

The synthesis and properties of acrylate-modified water-borne polyurethane emulsion

李庆 1樊增禄 1蔡信彬 1张龙 1赵晓剑1

作者信息

  • 1. 西安工程大学环境与化学工程学院,陕西西安710048
  • 折叠

摘要

Abstract

In order to improve the color fastness of ramie fabrics dyed by reactive dyes ,polyure‐thane prepolymer was enlarged by dimethylol propionic acid (DMPA ) and 1 ,4‐butanediol (BDO) ,isocyanate group(—NCO) of obtained product was reacted by hydroxyethyl methacry‐late(HEMA) to give a water‐borne polyurethane emulsion modified by HEMA .Then methyl methacrylate (MMA) is employed to copolymerize with obtained water‐borne polyurethane e‐mulsion to get an acrylate‐modified aqueous polyurethane color fixing agent .The properties of color fixing for ramie fabric is optimum when the amount of MAA is 24g ,modified polyure‐thane emulsion is 6.25mmol ,copolymerization temperature is 80℃ ,and copolymerization time is 80min .The wet rubbing fastness is improves significantly .

关键词

水性聚氨酯/丙烯酸酯/固色剂/染色牢度/苎麻织物

Key words

water-borne polyurethane/acrylate/fixer/color fastness/ramie fabric

分类

轻工纺织

引用本文复制引用

李庆,樊增禄,蔡信彬,张龙,赵晓剑..丙烯酸酯改性水性聚氨酯乳液的合成及性能[J].西安工程大学学报,2015,(2):140-145,6.

基金项目

陕西省国际科技合作项目(2014KW10-04);陕西省大学生创新训练项目 ()

西安工程大学学报

1674-649X

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