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活性炭纤维负载 Pd/Sn 电催化高浓度硝酸盐废水的优化研究

花莉 胡阳阳 张庚 贾卫华

陕西科技大学学报(自然科学版)Issue(1):30-35,45,7.
陕西科技大学学报(自然科学版)Issue(1):30-35,45,7.

活性炭纤维负载 Pd/Sn 电催化高浓度硝酸盐废水的优化研究

Optimization study of electrocatalytic reduction high concentration nitrate wastewater with activated carbon fiber loaded Pd/Sn

花莉 1胡阳阳 1张庚 1贾卫华2

作者信息

  • 1. 陕西科技大学资源与环境学院,陕西西安 710021
  • 2. 国家林业局林产工业规划设计院,北京100010
  • 折叠

摘要

Abstract

Activated carbon fiber loaded Pd/Sn (4∶1) was used as cathode in electrocatalytic reduction .Single factor and orthogonal experiments were employed to investigat the relation‐ships between nitrate removal ,nitrogen selectivity with current ,initial pH ,initial nitrate con‐centration and solution circulating velocity in high concentration nitrate wastewater ,and real‐ized optimum reaction condition .Results showed that the current ,interaction of current and initial pH were the major controlling factors of NO3 -‐N removal efficiency .The current and initial nitrate concentration were the major controlling factors of N2 selectivity .The optimiza‐ted reaction conditions were as follows :current 0 .68 A ,pH=6 .4 ,initial nitrate concentra‐tion 250 mg/L .In this conditions for 6 h ,the amount of NO3 -‐N removal from 250 mg/L to 200 mg/L ,maximum amount of N2‐N selectivity beyond 48% ,activity of electroeatalytic denitrification was 20 mg/(g · h) .

关键词

活性炭纤维负载Pd/Sn/电催化还原/高浓度硝酸盐废水/NO3 --N去除/N2 选择

Key words

activated carbon fiber loaded Pd/Sn/electric catalytic reduction/high concentra-tion nitrate wastewater/NO3--N removal/N2 selectivity

分类

资源环境

引用本文复制引用

花莉,胡阳阳,张庚,贾卫华..活性炭纤维负载 Pd/Sn 电催化高浓度硝酸盐废水的优化研究[J].陕西科技大学学报(自然科学版),2015,(1):30-35,45,7.

基金项目

国家自然科学基金项目(41003042);陕西省大学生创新创业训练计划项目 ()

陕西科技大学学报(自然科学版)

OACSTPCD

2096-398X

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