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复合纤维素酶水解对漂白马尾松纤维形态和结构的影响

李新平 王转 杜敏 王志杰 陈立红

陕西科技大学学报(自然科学版)Issue(2):1-6,18,7.
陕西科技大学学报(自然科学版)Issue(2):1-6,18,7.

复合纤维素酶水解对漂白马尾松纤维形态和结构的影响

Influence of complex cellulase hydrolysis on fiber morphology and structure of bleached masson pine

李新平 1王转 1杜敏 1王志杰 1陈立红2

作者信息

  • 1. 陕西科技大学轻工与能源学院陕西省造纸技术及特种纸品开发重点实验室,陕西 西安 710021
  • 2. 陕西科技大学化学与化工学院,陕西西安 710021
  • 折叠

摘要

Abstract

The effect of complex cellulase on the bleaching masson pine fiber surface ,mor‐phology parameter and structure was investigated .The results showed that increasing the time and dosage can enhance the degree of hydrolysis reaction within a certain range .The cel‐lulase preferentially acted on fines existed in the sample and on the surface of the fiber .With the increasing of dosage ,peeling and breaking occured ,fines content increased ,the average length increased at first and then gradually reduced .The degree of polymerization of the cel‐lulase and reaction efficiency was gradually decreased .When the dosage was 20 U · g‐1 ,the average length decreased by 70% ,fines content increased from 16 .8% to 72 .4% ,the degree of polymerization decreased by 53% .The crystallinity had a periodical change which in‐creased first and then decreased .Within a certain time ,the crystallinity showed that cellulase hydrolysed the amorphous at first ,then cellulase acted on the amorphous and crystallization zone at the same time ,but the crystal structure remained the typical cellulose I .

关键词

复合纤维素酶/酶水解/纤维形态/结晶度/聚合度

Key words

complex cellulase/enzymatic hydrolysis/fiber morphology/crystallinity/degree of polymerization

分类

化学工程

引用本文复制引用

李新平,王转,杜敏,王志杰,陈立红..复合纤维素酶水解对漂白马尾松纤维形态和结构的影响[J].陕西科技大学学报(自然科学版),2015,(2):1-6,18,7.

基金项目

国家自然科学基金项目(31370578);陕西省科技厅自然科学基础研究计划项目(2014JZ013);陕西省科技厅重点实验室科研计划项目(2011HBSZS014);陕西科技大学博士科研启动基金项目 ()

陕西科技大学学报(自然科学版)

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