陕西科技大学学报（自然科学版）Issue(4)：70-74,5.
新型含二茂铁基 Mannich 碱的合成与表征
Synthesis and characterization of novel Mannich bases containing ferrocenyl
摘要
Abstract
Two novel Mannich bases containing ferrocenyl were synthesized through Mannich reaction ,with acetyl ferrocene ,formaldehyde and substituted aniline as raw materials ,hydro‐chloric acid as catalyst ,anhydrous ethanol as solvent .Structures of new compounds were con‐firmed by IR ,1 H NMR ,13C NMR and elemental analysis .While a new method was explored for the synthesis of Mannich base containing ferrocenyl from liquid amine .The optimum re‐action conditions were determined by analyzing the effects of reaction temperature ,solvent , pH and the ratio of the starting materials:That is anhydrous ethanol as solvent ,the molar ra‐tio of acetyl ferrocene ,formaldehyde and substituted aniline is 1 .0∶3 .0∶3 .0 ,the reaction temperature is 80 ℃ ,pH of the reaction system is 4~6 .关键词
乙酰基二茂铁/M annich反应/M annich碱Key words
acetyl ferrocene/M annich reaction/M annich bases分类
化学化工引用本文复制引用
刘玉婷,宋思梦,尹大伟,杨晓刚..新型含二茂铁基 Mannich 碱的合成与表征[J].陕西科技大学学报（自然科学版）,2015,(4):70-74,5.基金项目
国家973科技计划前期专项项目（2014CB260411）；国家自然科学基金项目（21176148）；陕西省教育厅重点实验室科研计划项目 （）
