西北师范大学学报（自然科学版）Issue(1)：61-64,4.
BODIPY-苯酚类化合物的阴离子识别性能
Anion recognition properties based on BODIPY-phenol receptors
摘要
Abstract
Two BODIPY‐phenol derivatives 1 and 2 are designed and synthesized , and their anion recognition properties are investigated by UV‐Vis spectra technology . The results show that receptors 1 and 2 exhibit the selectivity for F - ,AcO - and H2 PO4 , w hich results in 186 and 133 nm red shift in absorption spectra , respectively , and the color changes from pink to light green . Receptors can interact with three anions by deprotonation with the affinity order :F- >AcO - > H2PO4- and 1>2 ,which can be ascribed to the basicity of special anions and the steric hindrance effect and electron‐donating conjugative effect of tert‐butyl group .关键词
BODIPY/苯酚/阴离子识别/脱质子化/特丁基Key words
BODIPY/phenol/anion recognition/deprotonation/tert-butyl group分类
化学化工引用本文复制引用
吕永军..BODIPY-苯酚类化合物的阴离子识别性能[J].西北师范大学学报（自然科学版）,2015,(1):61-64,4.基金项目
四川理工学院人才引进项目 （）
