西北师范大学学报(自然科学版)Issue(2):32-36,41,6.
物理吸附储氢的最佳条件分析
Optimum conditions for physisorption storage of hydrogen
摘要
Abstract
In this paper , the optimum storage conditions are discussed based on the Langmuir isotherm model . We analyze the adsorption equilibrium constant and elucidate the quantities involved . The effect of pressure , temperature and the heat of adsorption on the uptake‐release are discussed . As the equilibrium constant changes with temperature and the heat of adsorption exponentially , the uptake‐release capacity depends sensitively on them . For maximum delivery pressure between 50 to 100 bar and P1 = 1.5 bar at ambient temperature , an adsorption enthalpy change about - 33.5 kJ・mol - 1 is desired .关键词
储氢/物理吸附/Langmuir模型/最优条件Key words
hydrogen storage/physisorption/Langmuir model/optimum conditions分类
化学化工引用本文复制引用
陈宏善,刘鑫..物理吸附储氢的最佳条件分析[J].西北师范大学学报(自然科学版),2015,(2):32-36,41,6.基金项目
国家自然科学基金资助项目 ()