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用于锂离子电池的Fe3O4/C纳米结构的可控制备

邓洪贵 金双玲 詹亮 金鸣林 凌立成

新型炭材料Issue(4):301-308,8.
新型炭材料Issue(4):301-308,8.DOI:10.1016/S1872-5805(14)60139-6

用于锂离子电池的Fe3O4/C纳米结构的可控制备

Morphology-controlled synthesis of Fe 3 O 4/carbon nanostructures for lithium ion batteries

邓洪贵 1金双玲 2詹亮 1金鸣林 2凌立成1

作者信息

  • 1. 华东理工大学 化学工程联合国家重点实验室,上海 200237
  • 2. 上海应用技术学院 材料科学与工程学院,上海 201418
  • 折叠

摘要

Abstract

Morphology-controlled Fe3 O4 / carbon nanocomposites were synthesized by a solvothermal reaction followed by calcina-tion under a nitrogen atmosphere. Flower-like structures, dispersed nanoflakes and hollow microspheres could be readily obtained by adjusting the concentrations of the reactants. Based on the time-dependent structure evolution, a possible mechanism for the forma-tion of the different morphologies under various conditions was discussed. The lithium storage properties of the different Fe bon composites were compared. The flower-like sample shows the best electrochemical performance with the highest specific capaci-ty of 227 mAh/ g at a current rate of 5 C while hollow microspheres and dispersed nanoflakes have specific capacities of only 45 and 10 mAh/ g, respectively.

关键词

Fe3O4/纳米复合材料/负极材料/锂离子电池

Key words

Fe3 O4/Nanocomposite/Anode material/Lithium-ion battery

分类

信息技术与安全科学

引用本文复制引用

邓洪贵,金双玲,詹亮,金鸣林,凌立成..用于锂离子电池的Fe3O4/C纳米结构的可控制备[J].新型炭材料,2014,(4):301-308,8.

基金项目

国家自然科学基金(20806024,51002051) (20806024,51002051)

中央高校基本科研业务费专项资金(WA1014016).@@@@National Natural Science Foundation of China (20806024,51002051) (WA1014016)

Fundamental Research Funds for the Cen-tral Universities (WA1014016) (WA1014016)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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