新型炭材料Issue(2)：133-140,8.
电子受体材料功能化还原氧化石墨烯的结构和光学性能
Structure and optical property of functionalized reduced graphene oxides as electron acceptors in polymer solar cells
摘要
Abstract
Graphene oxide ( GO) prepared by the Hummers method was hydrothermally reduced for 5 and 10 h to obtain 5-RGO and 10-RGO, respectively. The GO and RGOs reacted with phenyl isocyanate to obtain three solution-processable functionalized graphenes ( SPFGO, 5-SPFRGO and 10-SPFRGO) , which were used as electron acceptors to prepare composite films with poly 3-hexylthiophene (P3HT) as an electron donor in polymer solar cells. Results indicate that GO consists of about 3-5 layers, and the RGOs still have some oxygen-containing functional groups such as —COOH and CO after the reduction. Functionalized GOs have good dispersibility in dichlorobenzene and exhibit energy levels matching P3HT, indicating that they can be used as the electron acceptor materials of polymer solar cells. A5-SPFRGO/P3HT composite film exhibits good compatibility, strong light absorption and obvious fluorescence quenching, suggesting that 5-SPFRGO is an excellent electron acceptor material.关键词
石墨烯/水热还原/功能化/受体/光学性能Key words
Graphene/Hydrothermal reduction/Functional/Acceptor/Optical performance分类
通用工业技术引用本文复制引用
屈腊琴,杨维佳,郝亚敏,杨永珍,刘旭光..电子受体材料功能化还原氧化石墨烯的结构和光学性能[J].新型炭材料,2015,(2):133-140,8.基金项目
国家自然科学基金(21176169) （21176169）
国家国际科技合作专项项目(2012DFR50460) （2012DFR50460）
山西省科技创新重点团队(201204011) （201204011）
山西省回国留学人员科技资助项目(2012-038).@@@@National Natural Science Foundation of China (21176169) （2012-038）
International ScienceňTechnology Cooperation Pro-gram of China (2012DFR50460) （2012DFR50460）
Shanxi Provincial Key Innovative Research Team in Technology (201204011) （201204011）
Shanxi Scholarship Council of China (2012-038) （2012-038）
