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Zn掺杂对 TiO2晶相及光催化性能的影响

徐向军 邢晓轲 卫世乾

信阳师范学院学报(自然科学版)Issue(2):248-251,4.
信阳师范学院学报(自然科学版)Issue(2):248-251,4.DOI:10.3969/j.issn.1003-0972.2015.02.022

Zn掺杂对 TiO2晶相及光催化性能的影响

Effect of TiO2 Doping by Zn on Crystalline Phase and Photocatalytic Activity

徐向军 1邢晓轲 2卫世乾3

作者信息

  • 1. 银川能源学院石油化工学院,宁夏银川750001
  • 2. 许昌职业技术学院园林园艺系,河南许昌461000
  • 3. 许昌学院学报编辑部,河南许昌461000
  • 折叠

摘要

Abstract

ZnO-TiO2 composite catalyst was prepared by modified sol-gel method.The microcrystalline structure and light absorption performance of ZnO-TiO2 were identified by XRD and UV-Vis DRS, respectively.With methyl or-ange( MO) as the degradation product, the result showed that the photocatalytic activity of ZnO-TiO2 was affected by the conversion time from sol to gel controlled by changing the content of water and ethanol.when the ratio of n( Zn)∶n( Ti) was 3∶15 and calcination temperature was 500 ℃, the degradation of MO was up to 96.4%under UV irradia-tion for 5 h.The XRD results confirmed ZnO-TiO2 appeared mostly anatase TiO2 and cubic Zn2 TiO4 phases, and the cubic Zn2 TiO4 phase was observed only when n( Zn)∶n( Ti)≥3∶15.Compared with the pure TiO2 , the characteristic absorption threshold of ZnO-TiO2 appeared slight blue shift.

关键词

ZnO-TiO2/Zn2 TiO4/溶胶-凝胶法/光催化

Key words

ZnO/GO/Zn2 TiO4/sol-gel method/photocatalytic

分类

化学化工

引用本文复制引用

徐向军,邢晓轲,卫世乾..Zn掺杂对 TiO2晶相及光催化性能的影响[J].信阳师范学院学报(自然科学版),2015,(2):248-251,4.

基金项目

国家自然科学基金项目 ()

信阳师范学院学报(自然科学版)

OA北大核心CSTPCD

1003-0972

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