云南化工Issue(3)：34-38,5.DOI:12.3969/j.issn.1004-275X.2015.03.010
羰基化合成甲酸钙实验安全分析及对策
Safety Analysis and Countermeasures of Carbonylation Synthesis of Calcium Formate from Carbon Monoxide and Calcium Hydroxide
马航 1冯霄 2杨亚斌 3曾波4
作者信息
- 1. 西安交通大学化学工程与技术学院，西安 710049
- 2. 云南省化工研究院，昆明 650228
- 3. 中国石油大学 北京 新能源研究院，北京 102249
- 4. 云南省化工研究院，昆明 650228
- 折叠
摘要
Abstract
The method using calcium carbide residue and carbon monoxide as raw materials to prepare calcium formate through the carbonylation synthesis route has become a research hot spot in China.However this experiment has great risk,because the reaction raw material CO is a flammable,explosive,toxic chemi-cal,and at the same time this reaction also requires high temperature,high pressure conditions.Therefore, before the experiments begin,the system safety must be carefully analyzed to develop appropriate safety oper-ation procedures.In this paper,the safety of test tank reactor devices are analyzed,the safety operation pro-cedures are proposed according to the analysis results.关键词
系统安全分析/安全操作规程/危险化学品/一氧化碳/应急预案Key words
system safety analysis/safety operation procedures/dangerous chemicals/carbon mon-oxide/emergency response plan分类
化学化工引用本文复制引用
马航,冯霄,杨亚斌,曾波..羰基化合成甲酸钙实验安全分析及对策[J].云南化工,2015,(3):34-38,5.
