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新型Ni-Fe(Ⅱ)普鲁士蓝/碳纳米管海绵去除 Cs +的研究

沈舞婷 李俊 康斌 常树全 戴耀东

原子能科学技术Issue(5):949-954,6.
原子能科学技术Issue(5):949-954,6.DOI:10.7538/yzk.2014.48.05.0949

新型Ni-Fe(Ⅱ)普鲁士蓝/碳纳米管海绵去除 Cs +的研究

Study of Removing Cs+ by Ni-Fe(Ⅱ) Prussian Blue/Carbon Nanotube Sponge

沈舞婷 1李俊 1康斌 1常树全 1戴耀东1

作者信息

  • 1. 南京航空航天大学 材料科学与技术学院,江苏 南京 211100
  • 折叠

摘要

Abstract

Ni-Fe(Ⅱ) Prussian blue/carbon nanotube sponge ,w hich has both adsorption and ion-exchange properties , was synthesized by combining the template and in-situ growth method .Then stable isotope of Cs was used to simulate radionuclide to study the adsorption effect of the composites .The results show that the sample has a three-dimensional porous structure as same as polyurethane foam . Moreover , the carbon nanotubes on the surface of sponge are successfully modified with Ni-Fe(Ⅱ ) Prussian blue .It shows that the ternary spongiform matrix contains 1.38% Ni-Fe(Ⅱ ) Prussian blue .Both ICP and Mössbauer spectrum analyses indicate that K + in Ni-Fe(Ⅱ) Prus-sian blue is exchanged by Cs+ ,and the absorption capacity is 698 μg/g .

关键词

Ni-Fe(Ⅱ)普鲁士蓝/碳纳米管海绵/Cs+

Key words

Ni-Fe(Ⅱ) Prussian blue/carbon nanotube sponge/Cs+

分类

资源环境

引用本文复制引用

沈舞婷,李俊,康斌,常树全,戴耀东..新型Ni-Fe(Ⅱ)普鲁士蓝/碳纳米管海绵去除 Cs +的研究[J].原子能科学技术,2014,(5):949-954,6.

基金项目

国家自然科学基金资助项目(81101146,11105073);江苏省环保厅科研课题资助项目(201151);江苏省自然科学基金资助项目(BK2011738,BK2011739,BK2012799);教育部博士学科点基金资助项目 ()

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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