中南民族大学学报（自然科学版）Issue(4)：20-25,6.
含1，3，4-噻二唑希夫碱衍生物及其金属配合物的合成和荧光性能研究
Synthesis and Luminescence of Schiff Base Derivatives Containing 1,3,4-Thiadiazole and Their Metal Complexes
摘要
Abstract
2-amino-5-(2-hydroxylphenyl)-1,3,4-thiadiazole was synthesized from salicylic acid and thiosemicarbazide with phosphorus oxychloride as solvent, cyclization reagent and catalyst.Then three schiff base compounds containing 1,3,4-thiadiazole and their metal complexes were formed by the reaction of 2-amino-5-(2-hydroxylphenyl)-1,3,4-thiadiazole and the corresponding aromatic aldehydes.These compounds were characterized by FT-IR and 1 H-NMR and the luminescence of the three schiff bases and their metal complexes were also studied.The results indicated that the synthesis was characterized by short reaction time, simple operation and high yield.The three schiff bases exhibited strong fluorescence emission spectrum and were expected to be of use as preferable organic photoelectric materials.关键词
水杨酸/氨基硫脲/1 ,3 ,4-噻二唑/光致发光/希夫碱Key words
salicylic acid/thiosemicarbazide/1,3,4-thiadiazole/luminescence/Schiff base分类
生物科学引用本文复制引用
吴腊梅,何为,李志有,张涛,蔡烨..含1，3，4-噻二唑希夫碱衍生物及其金属配合物的合成和荧光性能研究[J].中南民族大学学报（自然科学版）,2014,(4):20-25,6.基金项目
湖北省自然科学基金资助项目 （）
