中南民族大学学报（自然科学版）Issue(1)：27-32,6.
对位取代金属卟啉的合成及其催化氧化对甲基异丙苯的初步研究
The Synthesis of Metal Complexes of meso-tetra [ para-substituent phenyl] Porphyrins and Catalytic Oxidation of p-cymene
摘要
Abstract
Five meso-tetra [ para-substituent phenyl ] porphyrins ( TPPs ) were synthesized from para-substituent benzaldehyde and pyrrole in mixed solvent.The yields of the five TPPs ranged from 23%to 52%.These TPPs could react with metal ion (Co2+, Mn2+, Fe2+) and axial chloride ligand to produce a series of metalloporphyrins with high (90%~98%) yields.These TPPs and metalloporphyrins were characterized by1 H NMR, UV-Vis and infrared spectra.A novel solvent-free green oxidation process of p-cymene catalyzed by metalloporphyrins in the presence of molecular oxygen was developed for the first time.The results show that the T(p-Cl)PPCoCl and T(p-OCH3)PPCoCl presented better activities for p-cymene oxidation reactions than the other metalloporphyrins.关键词
合成/表征/催化氧化/对甲基异丙苯Key words
synthesis/characterization/catalytic oxidation/p-cymene分类
化学化工引用本文复制引用
吴腊梅,唐艳柳,孙志成,佘远斌..对位取代金属卟啉的合成及其催化氧化对甲基异丙苯的初步研究[J].中南民族大学学报（自然科学版）,2015,(1):27-32,6.基金项目
国家自然科学基金资助项目 （）
