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具有聚集诱导发光性能的四苯乙烯酰胺衍生物的合成与性能研究

罗妙 池振国

中山大学学报(自然科学版)Issue(1):74-78,5.
中山大学学报(自然科学版)Issue(1):74-78,5.DOI:10.1347/j.cnki.acta.snus.2015.01.015

具有聚集诱导发光性能的四苯乙烯酰胺衍生物的合成与性能研究

Synthesis and Properties of Tetraphenylethylene Derivatives with Aggregation-induced Emission and Different Self-assembly

罗妙 1池振国2

作者信息

  • 1. 湛江师范学院基础教育学院,广东 湛江 524037
  • 2. 中山大学化学与化学工程学院 聚合物复合材料及功能材料教育部重点实验室 光电材料与技术国家重点实验室,广东 广州 510275
  • 折叠

摘要

Abstract

As one class of the most important aggregation-induced emission materials,tetraphenylethyl-ene derivatives have been widely used in organic light-emitting diodes and sensors with excellent photo-physical and sensing properties.Tetraphenylethylene and 4-hexyloxybenzoic acid were combined together to synthesize a new compound with aggregation-induced emission (AIE)effect and self-assembly proper-ties.In this work,the thermal,photophysical and self-assembly properties were mainly characterized by UV-vis absorption spectroscopy,fluorescence spectroscopy,thermal gravimetric analysis,differential scanning calorimetry,polarizing optical microscopy (POM),and scanning electron microscopy.The re-sults showed that the compound emitted strong fluorescence,possessed high thermal stability,exhibited thermotropic liquid crystalline phase and formed different self-assembly structures.

关键词

四苯乙烯酰胺衍生物/聚集诱导发光/液晶性/自组装

Key words

tetraphenylethylene/aggregation-induced emission/liquid crystalline phase/thermal stabil-ity/self-assembly

分类

化学化工

引用本文复制引用

罗妙,池振国..具有聚集诱导发光性能的四苯乙烯酰胺衍生物的合成与性能研究[J].中山大学学报(自然科学版),2015,(1):74-78,5.

基金项目

国家“973”科技计划资助项目(2011CB606106-6);国家自然科学基金资助项目(51473185);广东省科技计划资助项目 ()

中山大学学报(自然科学版)

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