烟草科技Issue(8)：44-50,7.DOI:10.16135/j.issn1002-0861.20150809
1-O-[3-（2-呋喃基）丙烯酰基]-β-D-吡喃果糖的合成及应用
Synthesis and Application of 1-O-[3-(2-Furanyl)acryloyl]-β-D-fructopyranose
摘要
Abstract
In order to develop novel cigarette humectants, a new compound, Ⅷ, was designed and synthesized with D-fructose and furfural as starting materials. The structure of the product was characterized by IR, 1H NMR, 13C NMR, ESI-MS and elemental analysis. The moisture retentivity test, pyrolysis analysis, biological effects assessment of tobacco smoke were conducted after the product being applied to cigarette, and the sensory quality of cigarette was also evaluated. The results showed that: 1) The obtained product was proved to be the target compound 1-O-[3-(2-furanyl)acryloyl]-β-D-fructopyranose. 2) The moisture retentivity of Ⅷ was better than that of propylene glycol in dry environments. 3) Ⅷreleased aromatic furan constituents during pyrolysis. 4) The cigarettes added with Ⅷ were comparable to blank cigarettes in the biological effects of smoke. 5) Ⅷ reduced the dryness and irritation, increased the aroma, and improved the aftertaste of cigarette smoke.关键词
1-O-3-(2-呋喃基)丙烯酰基-β-D-吡喃果糖/合成/卷烟/保润剂/热裂解/烟气生物学效应/感官品质Key words
1-O-[3-(2-furanyl)acryloyl]-β-D-fructopyranose/Synthesis/Cigarette/Humectant/Pyrolysis/Biological effect of tobacco smoke/Sensory quality分类
化学化工引用本文复制引用
沈怡,冯广林,戴亚,孙玉峰,唐士军,陈昆燕..1-O-[3-（2-呋喃基）丙烯酰基]-β-D-吡喃果糖的合成及应用[J].烟草科技,2015,(8):44-50,7.基金项目
国家烟草专卖局2011年科技面上项目“卷烟双向保润技术的研究与开发”（11220119586，中烟办〔2011〕151号）。 （）
