岩矿测试Issue(4)：454-458,5.DOI:10.15898/j.cnki.11-2131/td.2015.04.013
酒石酸络合掩蔽锑-氢醌容量法测定锑矿石样品中的常量金
Determination of Gold in Antimony Ores by Hydroquinone Volumetric Method with Antimony Tartrate as Complexing and Masking Agent
张志刚 1刘凯 1陈泓 1冯瑞 1黄劲 1魏晶晶 1詹宝1
作者信息
- 1. 新疆地质矿产勘查开发局第一区域地质调查大队实验室，新疆 乌鲁木齐830013
- 折叠
摘要
Abstract
The traditional method of determining gold in antimony ores commonly includes sample digestion by aqua regia,preconcentration of gold by activated carbon,and measurement by hydroquinone volumetric technique. The traditional method suffers from the high contents of antimony,sulfur,arsenic,and mercury. Sulfur,arsenic, mercury,and carbon can be removed by stepwise heat,but antimony cannot be removed. In this study,tartaric acid is added to eliminate the interference of antimony. Adding tartaric acid to aqua regia during sample digestion can prevent proteolysis of antimony compounds as the acidity or temperature decreases. This step can ensure that the antimony quantity is less than 0. 3 mg after the ashing of activated carbon that has adsorbed gold. After being ashed,tartaric acid is again added in aqua regia to dissolve gold,eliminating the interference of antimony on gold during hydroquinone volumetric determination of gold. The proposed method suggests adding tartaric acid at the sample digestion stage is simple and rapid relative to the method of antimony elimination by hydrobromic acid and hydrochloric acid. The relative standard deviation of natural sample analysis is less than 5% and standard-addition recovery is 92 . 0% -107 . 0%.关键词
锑矿石/金/锑/酒石酸/活性炭富集/氢醌容量法Key words
antimony ore/gold/antimony/tartaric acid/activated carbon enrichment/hydroquinone volumetric method分类
化学化工引用本文复制引用
张志刚,刘凯,陈泓,冯瑞,黄劲,魏晶晶,詹宝..酒石酸络合掩蔽锑-氢醌容量法测定锑矿石样品中的常量金[J].岩矿测试,2015,(4):454-458,5.
