印染助剂2015，Vol.32Issue(7)：22-25,4.
含酰胺基阴离子型有机硅表面活性剂的合成及性能
Synthesis and properties of amide containing anionic silicone surfactants
摘要
Abstract
The aminopropyl trisiloxane was obtained from hexamethyldisiloxane and γ- aminopropyl meth-yl diethoxy silane as raw materials, and the tetramethyl ammonium hydroxide · pentahydrate as catalyst. The acylating agent succinic anhydride were reacted with 3- aminopropyl trisiloxane to obtain 4- oxo- (trisiloxane propylamino)- 2- succinate. The optimum reaction conditions were as fol ows: raw material mole ratio was 1.0:1.1, the raw material reacted at ice- cooling temperature for 2 h, then the mixture reacted at room tempera-ture for 2 h, the final product was obtained from 4- oxo- (trisiloxane propylamino)- 2- succinate and sodium bi-carbonate. The product structure and surface property was characterized by 1H- NMR and IR. The critical mi-cel e concentration (cmc) of the target products was 1.99×10- 3 mol/L. The surface tension (γcmc) was 29.4 mN/m. The new products had good softness for the fabric.关键词
4-(三硅氧烷-2-丙氨基)-4-氧代丁酸钠/合成/性能Key words
4- oxo- (trisiloxane propylamino)- 2- succinate/synthesis/properties分类
化学化工引用本文复制引用
邢凤兰,孙小龙,李旭,王超,王平郎..含酰胺基阴离子型有机硅表面活性剂的合成及性能[J].印染助剂,2015,32(7):22-25,4.基金项目
人力资源和社会保障部留学回国人员项目资助[2011]508 （）
