火炸药学报Issue(4)：13-17,5.DOI:10.14077/j.issn.1007-7812.2015.04.003
4-氨基-4″-硝基-［3，3′，4′，3″］-三呋咱（ANTF）的合成及工艺研究
Synthesis and Technology of 4-Amino-4″-nitro-[3,3′,4′,3″]-trifurazans (ANTF)
摘要
Abstract
The intermediate of 3 ,4-bis-(3′-aminofurazal-4′-yl)-furazan (BAFF-1 )was synthesized from 3 ,4-bis (3′-aminofurazal-4′-yl)-furoxan (BAFF)reduced by SnCl2·2H2O/CH3OH.4-Amino-4″-nitro-[3,3′,4′,3″]-trifurazans (ANTF)was successfully obtained through the reaction of BAFF-1 with Caro′s acid.The structure was character-ized by IR,NMR,MS spectra and elemental analysis.The influences of molar ratio of BAFF-1 to H2 O2 ,reaction time,reaction temperature and H2 O2 content on the yield of ANTF were studied.The optimum synthesis conditions were determined that the molar ratio ofn(BAFF-1)∶n(35%H2O2)∶n(H2SO4)was 1∶8∶40 for 4 hours at 30℃, the yield of ANTF is 45 .6%.The detonation velocity and detonation pressure of ANTF calculated by Kamlet formula are 8.20km/s and 29.64GPa,respectively under the density of 1.782g/cm3,it is expected to become a new type of melt-cast explosive to replace TNT.关键词
有机化学/ANTF/4-氨基-4″-硝基-3 ,3′,4′,3″-三呋咱/BAFF/呋咱化合物/高能量密度化合物Key words
organic chemistry/ANTF/4-amino-4″-nitro-[3 ,3′,4′,3″]-trifurazans/BAFF/furazan compound/high energy density compoud分类
军事科技引用本文复制引用
梁德辉,李鸿波,崔柏桦,易潜洪,张丽娟,张松,王志强,黄明,张勇,张光全..4-氨基-4″-硝基-［3，3′，4′，3″］-三呋咱（ANTF）的合成及工艺研究[J].火炸药学报,2015,(4):13-17,5.基金项目
国家重大专项（No．00402040103）；四川省大学生创新创业训练项目 （）
