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新型胺解原油降凝剂PSMA的合成与性能评价

于帅 于萍 魏云鹤 张宏民 张长桥

石油与天然气化工Issue(4):79-82,92,5.
石油与天然气化工Issue(4):79-82,92,5.DOI:10.3969/j.issn.1007-3426.2015.04.016

新型胺解原油降凝剂PSMA的合成与性能评价

Synthesis and properties evaluation of new aminated crude oil pour point depressant PSMA

于帅 1于萍 1魏云鹤 1张宏民 1张长桥1

作者信息

  • 1. 山东大学化学与化工学院
  • 折叠

摘要

Abstract

The copolymer poly(PSMA‐a) composed of maleic anhydride and octadecyl methacrylate was synthesized with dispersion copolymerization method by using polyvinylpylrrolidone (PVP) as the dispersant and ethanol as the dispersion medium .Then the polymer was amidated by aminobenzene . The structure and thermal stability of the final polymer (PSMA) were characterized by Fourier trans‐form infrared spectroscopy (FTIR) and thermal weight loss (TGA) .In this thesis ,the crude oil from Daqing Oilfield station was taken as the experimental subject ,the property of pour point depression and viscosity reduction were measured by differential scanning calorimetry (DSC) ,oil solidifying point tester and viscosity tester .Then ,the best ratio of monomer ,reaction temperature ,reaction time and dosage of initiator was determined through the orthogonal test .The results of the experi‐ment indicated that the best pour point depression and viscosity reduction effect were achieved when the amount of the PPD taken in the experiment was 750 mg/L and the PVP dosage was 8% of total monomer mass .

关键词

降凝剂/原油/分散聚合/热分析

Key words

pour point depressant/crude oil/dispersion polymerization/thermal analysis

分类

能源科技

引用本文复制引用

于帅,于萍,魏云鹤,张宏民,张长桥..新型胺解原油降凝剂PSMA的合成与性能评价[J].石油与天然气化工,2015,(4):79-82,92,5.

基金项目

国家重点基础研究发展计划(973计划)“高聚物减阻剂减阻机理与聚合过程理论研究及气敏测试元件”(2008CB617508)。 ()

石油与天然气化工

OA北大核心

1007-3426

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