石油与天然气化工Issue(4):79-82,92,5.DOI:10.3969/j.issn.1007-3426.2015.04.016
新型胺解原油降凝剂PSMA的合成与性能评价
Synthesis and properties evaluation of new aminated crude oil pour point depressant PSMA
摘要
Abstract
The copolymer poly(PSMA‐a) composed of maleic anhydride and octadecyl methacrylate was synthesized with dispersion copolymerization method by using polyvinylpylrrolidone (PVP) as the dispersant and ethanol as the dispersion medium .Then the polymer was amidated by aminobenzene . The structure and thermal stability of the final polymer (PSMA) were characterized by Fourier trans‐form infrared spectroscopy (FTIR) and thermal weight loss (TGA) .In this thesis ,the crude oil from Daqing Oilfield station was taken as the experimental subject ,the property of pour point depression and viscosity reduction were measured by differential scanning calorimetry (DSC) ,oil solidifying point tester and viscosity tester .Then ,the best ratio of monomer ,reaction temperature ,reaction time and dosage of initiator was determined through the orthogonal test .The results of the experi‐ment indicated that the best pour point depression and viscosity reduction effect were achieved when the amount of the PPD taken in the experiment was 750 mg/L and the PVP dosage was 8% of total monomer mass .关键词
降凝剂/原油/分散聚合/热分析Key words
pour point depressant/crude oil/dispersion polymerization/thermal analysis分类
能源科技引用本文复制引用
于帅,于萍,魏云鹤,张宏民,张长桥..新型胺解原油降凝剂PSMA的合成与性能评价[J].石油与天然气化工,2015,(4):79-82,92,5.基金项目
国家重点基础研究发展计划(973计划)“高聚物减阻剂减阻机理与聚合过程理论研究及气敏测试元件”(2008CB617508)。 ()