太原理工大学学报Issue(5)：483-488,6.DOI:10.16355/j.cnki.issn1007-9432tyut.2015.05.001
煤油共液化残渣制备中间相沥青及其表征
Preparation and Characterization of Mesophase Pitch from Coal and Oil Slurry Coliquefaction Residue
摘要
Abstract
In this study ,mesophase pitch was synthesized from two kinds of refined asphalt‐ene (A1 ,A2) extracted from Yanzhou coal and fluidized catalytic cracking slurry (FCCS) coliq‐uefaction residue (CLR1 ,CLR2) by pyrocondensation method at atmospheric pressure .Me‐sophase pitch was characterized by polarized optical microscopy (MOP) ,Fourier transform infra‐red spectrometry (FT‐IR) and scanning electron microscopy (SEM ) .The results show that A1 and A2 generated mesophase microspheres w hen hold at 380 ℃ for 10 h ,A1 sample formed ani‐sotropy flow domain when hold at 440 ℃ for 6 h ,while A2 sample formed bulk anisotropy me‐sophase when hold at 440 ℃ for 12 h .In addition ,the content of TI and QI of the mesophase pitch samples increased with the increase of temperature and holding time ,but the yield decreased contrarily .Research suggests that mesophase microbeads and needle coke could be produced from asphaltene of coliquefaction residue .关键词
共液化残渣/沥青质/热缩聚/中间相沥青Key words
coliquefaction residue/asphaltene/pyrocondensation polymerization/mesophase pitch分类
化学化工引用本文复制引用
冉娜妮,郭艳玲,高峰,何宏伟..煤油共液化残渣制备中间相沥青及其表征[J].太原理工大学学报,2015,(5):483-488,6.基金项目
煤转化国家重点实验室开放基金沥青烯基功能炭材料可控制备及其电化学性能研究（J13-14-904）；中国博士后科学基金纳米碳酸钙对环氧树脂／热塑性酚醛树脂固化行为的影响（2014M551059）；山西省自然科学基金资助项目气基还原煅烧煤系高岭土的研究 （）
