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海藻酸钠离子凝胶法制备直通孔氧化铝多孔陶瓷

孙阳 薛伟江 孙加林 周国治 黄勇

无机材料学报Issue(8):877-881,5.
无机材料学报Issue(8):877-881,5.DOI:10.15541/jim20150049

海藻酸钠离子凝胶法制备直通孔氧化铝多孔陶瓷

Porous Alumina Ceramics with Unidirectional Oriented Pores Fabricated by Ionotropic Process of Sodium Alginate

孙阳 1薛伟江 2孙加林 3周国治 1黄勇1

作者信息

  • 1. 北京科技大学材料科学与工程学院,北京100083
  • 2. 清华大学新型陶瓷与精细工艺国家重点实验室,材料科学与工程学院,北京 100084
  • 3. 清华大学新型陶瓷与精细工艺国家重点实验室,材料科学与工程学院,北京 100084
  • 折叠

摘要

Abstract

Alumina ceramic bodies with high porosity characterized by highly ordered and unidirectional oriented pores were successfully fabricated using the ionotropic process of sodium alginate by solvent exchange subsequently with freeze-drying. It is important to point out that the whole process and raw materials are eco-friendly. The average unidirectional pore size of samples sintered at 1500℃ for 2 h is 200μm with minor porosity in the pore walls with average pore size of 0.3-0.5μm. The properties of samples can be adjusted by controlling the solid loading in slurry. As the solid loading increasing from 5wt% to 15wt%, the density and compressive strength increased from 0.87 g/cm3 to 1.16 g/cm3 and from (18.9±3.2) MPa to (44.2±5.4) MPa, respectively with permeability de-creasing from 2.57×10-11m2 to 2.16×10-11m2. In addition, with the solid loading increasing from 5wt% to 15wt%, the conductivity of the direction parallel and perpendicular to the unidirectional pores increased from 2.1 W/(m·K) to 3.1 W/(m·K) and from 1.3 W/(m·K) to 1.7 W/(m·K), respectively.

关键词

直通孔氧化铝多孔陶瓷/渗透率/热导率/离子凝胶

Key words

unidirectionally oriented porous alumina ceramics/permeability/thermal conductivity/ionotropic

分类

化学化工

引用本文复制引用

孙阳,薛伟江,孙加林,周国治,黄勇..海藻酸钠离子凝胶法制备直通孔氧化铝多孔陶瓷[J].无机材料学报,2015,(8):877-881,5.

基金项目

国家重点基础研究发展计划(973计划)(2006CB605207-2) National Key Basic Research and Developmet Plan (973Plan)(2006CB605207-2) (973计划)

无机材料学报

OA北大核心CSCDCSTPCD

1000-324X

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