广东工业大学学报Issue(3)：133-136,146,5.DOI:10.3969/j.issn.1007-7162.2015.03.025
Bi-Si-B-O 系溶胶－凝胶玻璃及其熔融－淬火玻璃的结构对比
The Structure Comparison of Bi-Si-B-O Sol-Gel and Melt-quenching Glass
摘要
Abstract
The glassy powder of the Bi-Si-B-Zn-Al-O system is prepared by sol-gel and melt-quenching methods.The powder is characterized by means of XRD, SEM, EMAX, IR, DSC/TG, and the similari-ties and differences of the microstructure under different preparations are explored roughly.The results show that both of the two have amorphous structure.Compared with melt-quenching one, the glassy pow-der of sol-gel method can be broken easily , and the particle size in the range of 1~10μm is obtained af-ter ball milling, the element of which is relatively close to the designed.The network structures of the two kinds of glassy powder are similar, the [ BiO3 ] triangular, [ SiO4 ] tetrahedron and [ BO4 ] tetrahedron forming the glass′s basic network, but the melt-quenching glassy structure in [ SiO4 ] tetrahedron tends to be like framework, which makes the powder structure more stable, the glass transition temperature slight-ly higher than the sol-gel glass, and both of them are less than 600℃.关键词
溶胶-凝胶/熔融-淬火/Bi-Si-B-O玻璃体系/玻璃结构Key words
sol-gel/melt-quenching/Bi-Si-B-O glassy powder/glass structure分类
通用工业技术引用本文复制引用
李倩,袁鸽成,骆志捷,邓南林,张普..Bi-Si-B-O 系溶胶－凝胶玻璃及其熔融－淬火玻璃的结构对比[J].广东工业大学学报,2015,(3):133-136,146,5.基金项目
广东省科技计划项目（2006B14701003）；广东省企业资助项目 （）
