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渣油加氢催化剂酸性、孔结构及分散度对催化活性的影响

王爽 丁巍 赵德智 宋官龙 戴咏川

化工进展2015,Vol.34Issue(9):3317-3322,6.
化工进展2015,Vol.34Issue(9):3317-3322,6.DOI:10.16085/j.issn.1000-6613.2015.09.017

渣油加氢催化剂酸性、孔结构及分散度对催化活性的影响

Influence on catalytic activity in residue hydrogenation by acidity,pore structure and dispersion

王爽 1丁巍 1赵德智 2宋官龙 1戴咏川1

作者信息

  • 1. 辽宁石油化工大学化学化工与环境学部,辽宁 抚顺113001
  • 2. 中国石油大学(北京)重质油国家重点实验室,北京102249
  • 折叠

摘要

Abstract

Three methods for improving catalyst activities in residue hydrogenation were summarized. The modulation acidities are introduced by assistants on support,such as P,B and rare earth. The reaming effect of reaming agent,hydrothermal method and nano-assembly method on supports were presented. Furthermore,the role of surfactant on the dispersion of active metal was reviewed with CA and EDTA as a representative complexing agent. Besides,the application status of modified catalysts in residue hydrogenation process was reviewed,the development direction of new nano catalytic materials was pointed out,and then the development of catalysts was combined with modern analysis methods to do further mechanism research. It is expect to provide theoretical basis for modification research of hydrogenation catalyst,and also improve heavy oil treatment process.

关键词

酸性/孔结构/分散度/催化剂/活性

Key words

acidity/pore structure/dispersion/catalyst/activity

分类

能源科技

引用本文复制引用

王爽,丁巍,赵德智,宋官龙,戴咏川..渣油加氢催化剂酸性、孔结构及分散度对催化活性的影响[J].化工进展,2015,34(9):3317-3322,6.

基金项目

中国石油化工集团公司项目(030801)及中国海洋石油集团公司项目(20140331). (030801)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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