化工进展2015，Vol.34Issue(9)：3323-3330,8.DOI:10.16085/j.issn.1000-6613.2015.09.018
双功能催化剂在纤维素制多元醇中的研究进展
Reaserch progress in bifunctional catalysts for cellulose to polyols
摘要
Abstract
The research on heterogeneous bifunctional catalysts (BFC) is the hot theme in cellulose processing to obtain green chemicals. But in this process,the BFC still had some fatal problems needed to be solved,such as the mechanism of the catalytic process,and its low selectivity for aimed products and hydrothermal stability. The research progress in most concerned BFC containing active metal components,such as Ru,Ni,W,and Pt,and the interacts between metal components and carriers for the application in cellulose to hexabasic alcohols and low carbon polyols (C2-C3),were introduced, and the recent advances in mono-metallic,bi-metallic BFC and the BFC based on different carriers were simply summarized. The analysis results demonstrated the ratios of different metal components and the internal interacts between active metals and carriers had a great influence on catalytic results. The future study should be focused on the mechanism of interacts of catalytic constituents and carriers.关键词
生物质/降解/加氢/多元醇/双功能催化剂Key words
biomass/degradation/hydrogenation/polyols/bifunctional catalysts分类
化学化工引用本文复制引用
肖竹钱,欧阳洪生,葛秋伟,王珍珍,张金建,蒋成君,计建炳,毛建卫..双功能催化剂在纤维素制多元醇中的研究进展[J].化工进展,2015,34(9):3323-3330,8.基金项目
浙江省教育厅科研项目(Y20112088)及浙江省科技计划项目(2011R09028-10). （Y20112088）
