化工进展2015，Vol.34Issue(9)：3345-3348,3362,5.DOI:10.16085/j.issn.1000-6613.2015.09.021
NiO-LaCoO3催化剂的丙烷和CO氧化性能
Catalytic oxidation of carbon monoxide and propane on NiO-LaCoO3
摘要
Abstract
A series of NiO-LaCoO3were synthesized by solid-phase reaction method. The effects of calcination temperature and the content of Ni in catalyst on the carbon monoxide and propane oxidation performance of the as-synthesized catalysts were investigated. These catalysts were characterized by X-ray diffraction (XRD),hydrogen temperature-programmed reduction (H2-TPR) and other techniques. The results indicate that lower calcination temperature is beneficial for better catalytic performance. Among all catalysts,10NiO-LaCoO3calcinated at 700℃ exhibited the best catalytic performance. The addition of Ni into the structure of LaCoO3can significantly enhance the carbon monoxide and propane oxidation activity,and the optimal NiO loading is 7.5%. It was also found that the catalytic performance of catalysts is highly associated with oxygen mobility in catalysts.关键词
催化/催化剂载体/LaCoO3/镍/钙钛矿型催化剂Key words
catalysis/catalyst support/LaCoO3/nickel/perovskite type catalyst分类
化学化工引用本文复制引用
章轩语,陈忠,周颖,邢丰,胡庚申,罗孟飞..NiO-LaCoO3催化剂的丙烷和CO氧化性能[J].化工进展,2015,34(9):3345-3348,3362,5.基金项目
浙江省大学生新苗人才计划(2013R404042)及浙江省科技厅公益性项目(2013C31049). （2013R404042）
