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硫化汞光散射法检测环境水样中痕量汞

杨胜园 于军晖 杨慧仙 徐小娜 陈志英

南华大学学报(自然科学版)Issue(3):78-81,4.
南华大学学报(自然科学版)Issue(3):78-81,4.

硫化汞光散射法检测环境水样中痕量汞

Determination of Trace Mercury in Environmental Water with Mercuric Sulfide by Light Scattering Method

杨胜园 1于军晖 1杨慧仙 1徐小娜 1陈志英1

作者信息

  • 1. 南华大学 公共卫生学院,湖南 衡阳421001
  • 折叠

摘要

Abstract

A new Light Sattering ( RLS) method for the determination of trace Mercury in water was established. In alkaline medium,sodium sulphide ( Na2 S) reacted with mercury ions generated mercuric sulfide ( HgS) particles,resulting in the enhancement of light scat-tering intensity. At 468 nm wavelength,the intensity of light scattering was proportional to the concentration of mercury ion in the range of 2. 48 × 10 -10 ~6. 00 × 10 -9 mol/L. The linear regression equation was △I = 34 . 05 c + 14 . 2 with a correlation coefficient of 0. 9988, and the detection limit was 7. 44 × 10 -11 mol/L. The recovery rates were 98 . 80% ~103 . 00%.

关键词

硫化汞//光散射

Key words

Mercuric Sulphide/Mercury/Light Scattering

分类

化学化工

引用本文复制引用

杨胜园,于军晖,杨慧仙,徐小娜,陈志英..硫化汞光散射法检测环境水样中痕量汞[J].南华大学学报(自然科学版),2015,(3):78-81,4.

基金项目

国家自然科学基金资助项目(11205085) (11205085)

湖南省自然科学基金资助项目(14JJ3101) (14JJ3101)

南华大学学报(自然科学版)

1673-0062

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