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首页|期刊导航|苏州科技学院学报(自然科学版)|活性炭纤维对亚甲基蓝的吸附动力学和热力学研究

活性炭纤维对亚甲基蓝的吸附动力学和热力学研究

保佳媛 李峻峰 张钱丽 魏杰

苏州科技学院学报(自然科学版)Issue(3):30-35,6.
苏州科技学院学报(自然科学版)Issue(3):30-35,6.

活性炭纤维对亚甲基蓝的吸附动力学和热力学研究

Kinetics and thermodynamics of adsorption of methylene blue on the activated carbon Fiber

保佳媛 1李峻峰 2张钱丽 1魏杰2

作者信息

  • 1. 苏州科技学院 化学生物与材料工程学院,江苏 苏州 215009
  • 2. 江苏省环境功能材料重点实验室,江苏 苏州 215009
  • 折叠

摘要

Abstract

This paper studied the adsorption of methylene blue on activated carbon fiber (ACF) whose adsorp-tion ability was compared with granular activated carbon (GAC). The results show that ACF has better perfor-mance. The adsorption of methylene blue on ACF was explored from the aspects of thermodynamics and kinetics. Langmuir and Freundlich isotherm equations were linearized to evaluate the adsorption behavior. They were both suitable to analyze the equilibrium data for the adsorption of methylene blue on ACF. But the Langmuir model fitted better. Pseudo-first-order and pseudo-second-order action models for the adsorption of methylene blue on ACF were also determined. The pseudo-second-order kinetic model provided the better correlation. The thermo-dynamic parameters △Gθ、△Hθ and △Sθ were calculated. The result shows that the adsorption of methylene blue onto ACF is a spontaneous endothermic entropy increase process.

关键词

吸附/活性炭纤维/亚甲基蓝

Key words

adsorption/activated carbon fibe/methylene blue

分类

资源环境

引用本文复制引用

保佳媛,李峻峰,张钱丽,魏杰..活性炭纤维对亚甲基蓝的吸附动力学和热力学研究[J].苏州科技学院学报(自然科学版),2015,(3):30-35,6.

基金项目

国家自然科学基金资助项目(51178283);江苏省“六大人才高峰”资助项目;江苏省“高等学校大学生创新创业训练计划”资助项目 ()

苏州科技学院学报(自然科学版)

2096-3289

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