大学化学Issue(3):66-70,5.DOI:10.3866/pku.DXHX20150366
不同标态下标准电极电势间关系的热力学解释
The Thermodynamic Explanation of the Relationship between the Standard Electrode Potentials in Different Standard States
摘要
Abstract
Based on the relationship between the standard Gibbs free energy change, the standard electrode po-tential and the standard reaction equilibrium constant, the relationship between standard electrode potentials in differ-ent standard states has been analyzed. Accordingly, the general method to calculate the reaction equilibrium constant by designing a Galvanic battery is discussed, taking the dissociation equilibrium of water as an example.关键词
标准吉布斯自由能变化/标准电极电势/化学平衡常数Key words
Standard Gibbs free energy change/Standard electrode potential/Reaction equilibrium constant分类
化学化工引用本文复制引用
章应辉..不同标态下标准电极电势间关系的热力学解释[J].大学化学,2015,(3):66-70,5.基金项目
国家基础科学人才培养基金(No. J1103306) (No. J1103306)
南开大学2012年教育教学改革项目 ()