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生物质液化油分级产物的分离和综合利用研究

冯君锋 蒋剑春 徐俊明 贺小亮 杨中志 许乐

林产化学与工业Issue(6):61-68,8.
林产化学与工业Issue(6):61-68,8.DOI:10.3969/j.issn.0253-2417.2014.06.010

生物质液化油分级产物的分离和综合利用研究

Separation and Utilization of Classification Products in Liquefied Oil of Biomass

冯君锋 1蒋剑春 1徐俊明 2贺小亮 1杨中志 2许乐1

作者信息

  • 1. 中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京 210042
  • 2. 江苏强林生物能源材料有限公司,江苏 溧阳 213364
  • 折叠

摘要

Abstract

Liquefaction of biomass using concentrated sulfuric acid as catalyst and methanol-glycerol complex as solvent was investigated. The liquefied products from bamboo shavings, poplar, eucalyptus and pine were neutralized, filtrated and followed by rotary evaporation. The results show that the product from liquefaction of bamboo shaving are mixture of phenolics and acetyl methyl glucoside. Polyglycoside phase mainly contains about 41. 81 % of polyglycosides which were mainly pyranoside, and 47. 27 % of unreacted glycerin and glycerin polymers. On the other hand, polyphenol phase mainly contains levulinate, polyphenols, and glycerol, and the content of glycerine and its polymers is 38. 04 %. Polyphenols mainly contain phenols and levulinic acid esters, and the average molecular weight of phenolics is approximate 990.

关键词

生物质液化/多糖苷/乙酰丙酸甲酯/杂多酚

Key words

biomass liquefaction/multi-glucoside/acetyl methyl propionate/polyphenols

分类

化学化工

引用本文复制引用

冯君锋,蒋剑春,徐俊明,贺小亮,杨中志,许乐..生物质液化油分级产物的分离和综合利用研究[J].林产化学与工业,2014,(6):61-68,8.

基金项目

国家林业局公益性行业专项(201204801) (201204801)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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