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酸催化水解生物质产乙酰丙酸的现状分析

王琼 庄新姝 袁振宏 许敬亮 亓伟 余强

林产化学与工业Issue(6):155-164,10.
林产化学与工业Issue(6):155-164,10.DOI:10.3969/j.issn.0253-2417.2014.06.025

酸催化水解生物质产乙酰丙酸的现状分析

Research Status Analysis of Acid Catalyzed Hydrolysis of Biomass to Levulinic Acid

王琼 1庄新姝 2袁振宏 1许敬亮 1亓伟 1余强1

作者信息

  • 1. 中国科学院广州能源研究所,中国科学院可再生能源重点实验室,广东 广州 510640
  • 2. 中国科学院大学,北京 100049
  • 折叠

摘要

Abstract

This paper discussed the research status of acid catalyzed hydrolysis of biomass to levulinic acid ( LA ) with three aspects i. e. sources of raw materials, processes and reactors, and catalytic mechanism. Especially in the field of catalytic mechanism, it gradually analyzed the mechanism of LA production from cellulose to sugars, sugars to 5-hydroxymethylfurfural (5-HMF), and 5-HMF to LA, and the mechanism of LA production directly from glucose, as well as the demonstration of the kinetics of LA production from microcrystalline cellulose under dilute hydrochloric acid and dilute sulfuric acid environments, followed by the kinetics and mechanism analysis of degradation of typical biomass in the dilute acid. This paper aims to provide sufficient information for relative scholars to carry out researches on LA production from biomass, and help scholars to conduct selective research.

关键词

乙酰丙酸/生物质/稀酸/催化机理

Key words

levulinic acid/biomass/dilute acid/catalytic mechanism

分类

化学化工

引用本文复制引用

王琼,庄新姝,袁振宏,许敬亮,亓伟,余强..酸催化水解生物质产乙酰丙酸的现状分析[J].林产化学与工业,2014,(6):155-164,10.

基金项目

国家863计划资助(2012AA051802) (2012AA051802)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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