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离子交换树脂对铀的静态和动态吸附行为研究

胡鄂明 张皖桂 王清良 邵二言 梁建龙

南华大学学报(自然科学版)Issue(2):42-46,5.
南华大学学报(自然科学版)Issue(2):42-46,5.

离子交换树脂对铀的静态和动态吸附行为研究

Study of Ion Exchange Resin’s Static and Dynamic Adsorption Behavior for Uranium(Ⅵ)

胡鄂明 1张皖桂 1王清良 1邵二言 1梁建龙1

作者信息

  • 1. 南华大学 铀矿冶生物技术国防重点学科实验室,湖南 衡阳421001
  • 折叠

摘要

Abstract

A Ф40 mm × 1200 mm adsorption device was used to simulate the actual urani-um hydrometallurgy process in industrial production,with the breakthrough curve got in an ion exchange adsorption fixed bed and the static adsorption experiment was carried out to measure equilibrium adsorption quantity under different concentration. Freundlich and Langmuir adsorption isotherm models are applied to fit experimental equilibrium data, which shows that both are suitable to describe the adsorption of ion exchange resin for ura-nium and the process of the adsorption of uranium is controlled by liquid film diffusion and hole diffusion together,and the dynamic adsorption capacity is about 1. 87 times that of the static adsorption capacity. Bohart Adams model and Wolborska model are carried out on the breakthrough curve fitting,of which the correlation coefficients are above 0. 92,the er-ror between resin adsorption capacity of model and Liquid method is small. This article puts forwar a point to explain the difference between the static adsorption and dynamic ad-sorption.

关键词

离子交换/树脂/动态吸附/静态吸附/

Key words

ion exchange/resin/dynamic adsorption/static adsorption/uranium

分类

能源科技

引用本文复制引用

胡鄂明,张皖桂,王清良,邵二言,梁建龙..离子交换树脂对铀的静态和动态吸附行为研究[J].南华大学学报(自然科学版),2015,(2):42-46,5.

基金项目

湖南省科技厅基金资助项目(2012sk3155) (2012sk3155)

南华大学学报(自然科学版)

1673-0062

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