物理学报Issue(9)：1-9,9.DOI:10.7498/aps.64.098702
基于可调控多肽纳米管和石墨烯复合纳米结构的光吸收催化平台∗
A photo catalysis system based on comp osite nanostructures of controlable p eptide nanotub es and graphene
摘要
Abstract
Self-assembly is the way that is used by Mother Nature to create complex materials of hierarchical shapes and diverse functionalities. The photosynthesis apparatus of plant is an example of such complex materials that can direct convert the sunlight energy into chemical energy. Inspired by this, many artificial photosynthesis systems have been successfully engineered. However, most of these systems were based on only one type of simple nanostructure, such as nanosphere or nanotube. The charge separation and exciton transfer in such systems may be further improved by combining multiple nano-structures. Here, we report a novel photo catalysis system based on composite nanostructures of controllable peptide nanotubes and graphene. We use the mixture of diphenylalanine (FF) and carboxyl graphene for the photo catalysis because they are stable under different solvent conditions and highly conductive, which can provide more paths for exciton transfer. Moreover, the diameters of the peptide nanotubes become thinner in the presence of carboxyl graphene, leading to a more uniformly distributed system than simply using the peptide nanotubes alone. The FF peptide nanotubes can connect with the carbonyl graphene (CG) to form the composite nanostructures because of the π-π stacking interaction between benzene rings of FF and conjugated π bond of CG. The composite nanostructures of controllable peptide nanotubes and graphene provide more transmission channels for the excitions since they can travel on the nanotubes, CG or the compound of the both. We also demonstrate that when the photo-harvesting ruthenium complex and catalytic platinum nanoparticles are deposited on the system, the nicotinamide adenine dinucleotide (NADP+) can reduce to NADPH. The catalytic efficiency and rate are much higher than thaose of other artificial photosynthesis systems reported in the literature. Surprisingly, we find that the catalytic efficiency of the combined system is better than the sum of separated systems with only FF nanotubes or carboxyl graphene. The high turnover frequency, high reaction rate, and low toxicity of this artificial photosynthesis system will make the combined system attractive for large-scale applications, including optoelectronic industry, energy industry, etc.关键词
多肽纳米管/羧基石墨烯/光吸收/催化Key words
peptide nanotubes/carboxyl graphene/light harvesting/photocatalysis引用本文复制引用
薛斌,王洪阳,秦猛,曹毅,王炜..基于可调控多肽纳米管和石墨烯复合纳米结构的光吸收催化平台∗[J].物理学报,2015,(9):1-9,9.基金项目
国家重点基础研究发展计划(973计划)(批准号:2013CB834100)和国家自然科学基金(批准号:11334004,91127026)资助的课题.* Project supported by the National Basic Research Program of China (Grant No.2013CB834100), and the National Natural Science Foundation of China (Grant No.11334004,91127026) （973计划）
