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脉冲电流对AZ21镁电极电压滞后的影响

邓玲 陈琳 杨巧玲 陈昌国

工程科学学报Issue(10):1358-1363,6.
工程科学学报Issue(10):1358-1363,6.DOI:10.13374/j.issn2095-9389.2015.10.016

脉冲电流对AZ21镁电极电压滞后的影响

Influence of pulse current on the voltage delay of AZ21 magnesium electrode

邓玲 1陈琳 1杨巧玲 2陈昌国3

作者信息

  • 1. 重庆大学化学化工学院,重庆400044
  • 2. 四川理工学院材料与化学工程学院,自贡643000
  • 3. 材料腐蚀与防护四川省重点实验室,自贡643000
  • 折叠

摘要

Abstract

A surface film generates on AZ21 magnesium alloy in magnesium sulfate solutions, resulting in serious voltage delay. Pulse current is conducive to the application of AZ21 magnesium alloy in a battery, for it can shorten the lag time, reduce the initial discharge voltage drop and increase the discharge stability. The voltage delay of AZ21 magnesium alloy in a 2 mol·L-1 MgSO4 solution was investigated by chronopotentiometry, multi-current steps, electrochemical impedance measurement, and scanning electron micros-copy. After a 50 mA pulse current was applied for 1 s, the voltage lag time of AZ21 magnesium alloy decreased from 6. 35 s (3. 23 V) to 0. 59 s (0. 034 V).

关键词

镁合金/表面膜/电压/迟滞/脉冲电流

Key words

magnesium alloys/surface films/voltage/delay/pulse current

分类

矿业与冶金

引用本文复制引用

邓玲,陈琳,杨巧玲,陈昌国..脉冲电流对AZ21镁电极电压滞后的影响[J].工程科学学报,2015,(10):1358-1363,6.

基金项目

国家自然科学基金资助项目(21273292) (21273292)

材料腐蚀与防护四川省重点实验室开放基金项目(2014CL12) (2014CL12)

工程科学学报

OA北大核心CSCDCSTPCD

2095-9389

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