储能科学与技术Issue(4):402-409,8.DOI:10.3969/j.issn.2095-4239.2013.04.008
电化学基础(Ⅴ)--电极过程动力学及电荷传递过程
Fundamentals of electrochemistry(Ⅴ)-Electrochemical kinetic and charge-transfer process for electrochemical reaction
摘要
Abstract
The charge-transfer process is the basis of an electrochemical reaction. The knowledge about charge-transfer processes can help us to recognize to the inherent nature through the electrochemical reaction representation, and to achieve the control in the electrochemical industry and the electrochemical reaction design. In this paper, we reviewed the scientific background of electrochemical kinetic and development of the charge-transfer process, and rethought about their scientific idea. We believe that a historical review can be very helpful for our future research.关键词
电化学/电荷传递/塔菲尔公式/巴特勒-沃尔默公式/量子力学机理Key words
electrochemistry/charge transfer/Tafel equation/Bulter-Volmer equation/quantum mechanism分类
自科综合引用本文复制引用
贾志军,马洪运,吴旭冉,廖斯达,王保国..电化学基础(Ⅴ)--电极过程动力学及电荷传递过程[J].储能科学与技术,2013,(4):402-409,8.基金项目
化学工程联合国家重点实验室2011年自主课题立项,国家自然科学基金项目(21076112,21276134)。 ()