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Ba2 SiO4:Ce3+,Mn2+荧光粉的制备与光谱性质

孙晓园 张丽宏 于立军 骆永石 吴春雷 贺小光 张家骅

发光学报Issue(12):1416-1421,6.
发光学报Issue(12):1416-1421,6.DOI:10.3788/fgxb20153612.1416

Ba2 SiO4:Ce3+,Mn2+荧光粉的制备与光谱性质

Preparation and Photoluminescence Properties of Ba2 SiO4:Ce3+,Mn2+ Phosphor

孙晓园 1张丽宏 1于立军 1骆永石 2吴春雷 3贺小光 1张家骅2

作者信息

  • 1. 长春师范大学 物理学院,吉林 长春 130032
  • 2. 发光学及应用国家重点实验室 中国科学院长春光学精密机械与物理研究所,吉林 长春 130033
  • 3. 牡丹江师范学院 理学院,黑龙江 牡丹江 157011
  • 折叠

摘要

Abstract

The phosphors Ba2SiO4∶xCe3+,yMn2+(x =0 -0. 2, y =0 -0. 15) were synthesized through the solid-state reaction technique. The structure, photoluminescence properties of these phosphors were described. Under the excitation of UV light, the emission spectra of Ba2 SiO4∶xCe3+show broad band around 384 nm. The emission spectra of Ba2 SiO4∶ Mn2+ show broad band around 376 nm, and the red emission is very weak. The red emission band located at around 606 nm is strongly enhanced in Ba2SiO4∶xCe3+,yMn2+, which is arised from 4T1(4G)-6A1(6S) transition of Mn2+. The results show that a part of the energy of Ce3+ ion is transferred to Mn2+ ion and sensitizes the luminescence of Mn2+ ion effectively. When the mole fractions of Ce3+ and Mn2+ are 0. 2 and 0. 075, the red emission around 606 nm is the strongest.

关键词

荧光粉/光致发光/能量传递

Key words

phosphor/photoluminescence/energy transfer

分类

数理科学

引用本文复制引用

孙晓园,张丽宏,于立军,骆永石,吴春雷,贺小光,张家骅..Ba2 SiO4:Ce3+,Mn2+荧光粉的制备与光谱性质[J].发光学报,2015,(12):1416-1421,6.

基金项目

国家自然科学基金青年科学基金(51202019)资助项目 ()

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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