高等学校化学学报Issue(11)：2087-2098,12.DOI:10.7503/cjcu20150747
电化学表面增强拉曼光谱的量子化学研究
Quantum Chemistry Study of Electrochemical Surface-enhanced Raman Spectroscopy
摘要
Abstract
Considering the study of electrochemical surface adsorption and reaction processes at the molecular level, Surface-enhanced Raman spectroscopy( SERS) shows its particular merits and provides a powerful tech-nical method for this study. However, the mechanism of enhancement needs to be further explored. This re-view summarizes the systematic work on electrochemical SERS ( EC-SERS ) by combining quantum chemistry calculations. On the basis of these studies, we can make deep insight for extracting the physical and chemical information in EC-SERS spectra. Focusing on adsorption of pyridine on the electrochemical surface, adsorption and reactional process of water on the surface, and surface coupling reaction for p-aminothiophenol, we had illustrated the nature of the adsorption and photochemical reactions on the electrochemical surface.关键词
量子化学/表面增强拉曼光谱/电荷转移态/表面等离激元共振/电化学Key words
Quantum chemistry/Surface-enhanced Raman spectroscopy/Charge transfer state/Surface plasmon resonance/Electrochemistry分类
化学化工引用本文复制引用
庞然,金曦,赵刘斌,丁松园,吴德印,田中群..电化学表面增强拉曼光谱的量子化学研究[J].高等学校化学学报,2015,(11):2087-2098,12.基金项目
国家自然科学基金(批准号:21373712,21321062,21533006)、国家重点基础研究项目(批准号:2015CB932303)和厦门大学固体表面物理化学国家重点实验室开放基金(批准号:201416)资助.覮 Supported by the National Natural Science Foundation of China(Nos.21373712,21321062,21533006), the National Basic Research Program of China(No.2015CB932303), and the Open Funds of State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, China(No.201416) （批准号:21373712,21321062,21533006）
