高等学校化学学报Issue(11)：2115-2133,19.DOI:10.7503/cjcu20150601
含全碳和多炔阴离子配体的银簇化合物的超分子组装及其结构研究
Assembly of Organosilver(I) Networks with Multinuclear Supramolecular Synthons Containing All-carbon and Carbon-rich Anionic Ligands
摘要
Abstract
This review summarizes recent advances conducted by our group on related silver complexes of ( a) all-carbon ligands C2-6 and C2-8 , (b) 1,5-hexadiyne-1,6-diide C6H2-4 , (c) ethynediide C2-2 and ethynide R—C-2 assembled with phosphonic acids, ( d) aryl, alicyclic and heteroaromatic ethynides, and ( e) ethynides that are sta-bilized by different types of silver…carbon binding interactions in the crystalline state, which are further consolidated by weak intra/intermolecular forces. The effects of the solvent, bulkiness of ligands and ancillary ligands on the construction of coordination networks are also discussed.关键词
全碳配体/亲银作用/多炔配体/炔基/银簇网络结构/超分子合成子Key words
All-carbon ligand/Argentophilicity/Carbon-rich ligand/Ethynide/Organosilver (I) network/Supramolecular synthon分类
化学化工引用本文复制引用
侯俊傑,胡婷,譚耀新,麥松威..含全碳和多炔阴离子配体的银簇化合物的超分子组装及其结构研究[J].高等学校化学学报,2015,(11):2115-2133,19.基金项目
香港研究资助局项目(批准号:CUHK 402408,402710)和伟伦基金会项目资助 （批准号:CUHK 402408,402710）
