高师理科学刊Issue(9)：42-45,4.DOI:10.3969/j.issn.1007-9831.2015.09.013
由1，4对苯二甲酸和多氮杂环配体构筑的镉配合物的合成及晶体结构
A Cadmium(II)complex based on 1,4-benzenedicarboxylic acid and 4′-(4″-pyridyl)-2,2′:6′,2″-terpyridine:synthesis and structure
摘要
Abstract
A cadmium(II)complex [Cd2(1,4-BDC)(4-pytyp)(H2O)4]·(1,4-BDC)(1)(1,4-H2BDC=1, 4-benzenedicarboxylic acid;4-pytyp = 4′-(4″-pyridyl)-2,2′∶6′,2″-terpyridine)has been synthesized under hydrothermal conditions and was characterized by X-ray diffraction single crystal structure analysis,elemental analysis and IR spectra.The title complex crystallizes in Triclinic P-1 space group witha=0.9923(2)nm, b=1.0703(2) nm,c=1.292 5(3) nm,α=74.50(3)º,β=78.61(3)º,γ=69.18(3)º.The complex was formed to a 3D supramolecular network linked byπ-π stacking interactions and hydrogen bonds.Meanwhile, thermogravimetric analysis of the complex was analysized in detail.关键词
镉配合物/混合配体/晶体结构/水热合成Key words
cadmium complex/mixed ligand/crystal structure/hydrothermal synthesis分类
化学化工引用本文复制引用
刘园园,蒋恩慧,祝贺,宋宁,张兴晶..由1，4对苯二甲酸和多氮杂环配体构筑的镉配合物的合成及晶体结构[J].高师理科学刊,2015,(9):42-45,4.基金项目
新世纪优秀人才项目（NCET-10-0176）；吉林省教育厅“十二五”科学技术研究项目（吉教科合字2014第154号）；吉林师范大学硕博启动基金项目 （）
