化工进展2015，Vol.34Issue(12)：4320-4323,4.DOI:10.16085/j.issn.1000-6613.2015.12.031
γ-叔丁基过氧丙基三甲氧基硅烷的制备及表征
Synthesis and characterization of γ-tert-butyl peroxide propyltrimethoxysilane
摘要
Abstract
Theγ-tert-butyl peroxide propyltrimethoxysilane was synthesized withtert-butyl hydroperoxide and 3-chloropropyltrimethoxysilane,catalyzed by ferric chloride in toluene for the first time. The product was characterized by IR、1H NMR and mass spectra,and its structure was determined. Synthetic conditions such as the catalyst species,the reactants ratio,the reaction temperature and time were discussed. The optimal conditions were determined as follows:n(tert-butyl hydroperoxide):n(3-chloropropyltrimethoxysilane)=1.2:1,m(catalyst):m(3-chloropropyltrimethoxysilane) =0.015:1,reaction temperature of 40℃and reaction time of 8h. The yield of the product could reach 42% under the optimal reaction condition.关键词
过氧化氢叔丁醇/γ-叔丁基过氧丙基三甲氧基硅烷/合成/催化剂/优化Key words
tert-butyl hudroperoxide/γ-tert-butyl peroxide propyltrimethoxysilane/synthesis/catalyst/optimization分类
化学化工引用本文复制引用
马立群,何子健,孙兆洋,常海洋,陈国力,王雅珍..γ-叔丁基过氧丙基三甲氧基硅烷的制备及表征[J].化工进展,2015,34(12):4320-4323,4.基金项目
国家自然科学基金项目(21376127). （21376127）
