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刚性与柔性连接的骨架型二芳烯聚合物

张诗曼 张复实 邓爱明

化工学报Issue(11):4716-4721,6.
化工学报Issue(11):4716-4721,6.DOI:10.11949/j.issn.0438-1157.20150400

刚性与柔性连接的骨架型二芳烯聚合物

Backbone diarylethene polymers with rigid and flexible structures

张诗曼 1张复实 2邓爱明3

作者信息

  • 1. 西南技术工程研究所,重庆 400039
  • 2. 清华大学化学系,北京 100084
  • 3. 清华大学化学系,北京 100084
  • 折叠

摘要

Abstract

With diarylethene as one co-monomer, two backbone diarylethene polymers were synthesized through convenient routes. The solubility, photochromism and fatigue resistant property were studied. The two obtained polymers showed the reversible photochromic ability and excellent fatigue resistance. In the synthesis process of the two polymers, diarylethene and copolymer units were connected using rigid and flexible connections, respectively, and thus obtained diarylethene polymers with different spectral properties and molecular weight.

关键词

光化学/光致变色/聚合物/合成/抗疲劳性

Key words

photochemistry/photochromism/polymers/synthesis/fatigue resistance

分类

化学化工

引用本文复制引用

张诗曼,张复实,邓爱明..刚性与柔性连接的骨架型二芳烯聚合物[J].化工学报,2015,(11):4716-4721,6.

基金项目

国家自然科学基金项目(21273127);国家自然科学基金委员会-中国工程物理研究院联合基金项目(U1230129)。@@@@supported by the National Natural Science Foundation of China (21273127) and the National Natural Science Foundation of China& China Academy of Engineering Physics (U1230129) (21273127)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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