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综合风化条件下渤海原油中PAHs变化特征研究

曹磊 韩彬 郑立 杨东方 王小如

海洋科学Issue(2):48-55,8.
海洋科学Issue(2):48-55,8.

综合风化条件下渤海原油中PAHs变化特征研究

Changes of polycyclic aromatic hydrocarbons(PAHs)in the crude oil from Bohai Sea under comprehensive weathering condition

曹磊 1韩彬 2郑立 1杨东方 3王小如1

作者信息

  • 1. 国家海洋局 第一海洋研究所,山东 青岛 266061
  • 2. 上海海洋大学 水产与生命学院,上海 201306
  • 3. 大连理工大学 海岸和近海工程国家重点实验室,辽宁 大连116024
  • 折叠

摘要

Abstract

This paper presents the changes of polycyclic aromatic hydrocarbons(PAHs) in the crude oil from Bohai Sea under comprehensive weathering condition. The results showed that the distribution patterns of PAHs in crude oil had great changes after 50 days weathering. Naphthalene (NAP) series compounds had the most serious loss and loss of the relative concentration reached 56.78%, while the proportion of phenanthrene (PHE) series compounds has increased in some extent. Dibenzothiophene (DBT) series, chrysene (CHR) series and fluorene (FLU) series remained relatively stable. The disciplines of PAHs distribution can lead to screen out new diagnostic ratios for oil spill identification. The customary six diagnostic ratios were proved to have strong weathering-resistant capabilities under the synthetical weathering conditions and they can be used for source identification of weathered oil.

关键词

原油/多环芳烃/风化/诊断比值

Key words

crude oil/PAHs/weathering/diagnostic ratio

分类

化学化工

引用本文复制引用

曹磊,韩彬,郑立,杨东方,王小如..综合风化条件下渤海原油中PAHs变化特征研究[J].海洋科学,2013,(2):48-55,8.

基金项目

大连理工大学海岸和近海工程国家重点实验室开放基金项目(LP1012) (LP1012)

海洋公益性行业科研专项(201205012) (201205012)

国家海洋局近岸海域生态环境重点实验室开放研究基金项目(200908) (200908)

海洋科学

OA北大核心CSCDCSTPCD

1000-3096

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