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从废旧碱性锌锰电池极性材料中浸出锌的试验研究

孙铜 伍碧 彭蜀君 孙维义 丁桑岚 苏仕军

湿法冶金Issue(4):252-255,4.
湿法冶金Issue(4):252-255,4.

从废旧碱性锌锰电池极性材料中浸出锌的试验研究

Experimental Reseach on Leaching of Zinc From Electrode Material in Spent Alkaline Zn-Mn Battery

孙铜 1伍碧 1彭蜀君 1孙维义 1丁桑岚 1苏仕军1

作者信息

  • 1. 四川大学建筑与环境学院,四川成都 610065
  • 折叠

摘要

Abstract

The leaching of zinc from electrode materials of spent alkaline Zn-Mn battery using acids was not ideal ,and it was difficult to separate zinc from manganese in leaching solution .The leaching mechanism of zinc from electrode materials in ammonia and NH3 · H2 O-(NH4 )2 SO4 system respectively were investigated . The results showed that in ammonia system ,the leaching rate of zinc only reached 45% when the electrode materials were leached for 40 min at room temperature using 25% ammonia aqueous solution at V(liquid)∶m(solid) of 15∶1 .After adding (NH4)2SO4 into ammonia aqueous system ,the leaching rate of zinc reached 96% when the electrode materials were leached for 20 min at the conditions of room temperature ,(N H4 )2 SO4 mass concentration of 200 g/L and V (liquid)∶ m(solid) of 15∶1 using 25% ammonia aqueous solution .

关键词

废旧碱性锌锰电池/极性材料/氨水-硫酸铵体系//浸出

Key words

spent alkaline Zn-Mn battery/electrode materials/ammonia-(NH4 )2 SO4 system/zinc/leaching

分类

矿业与冶金

引用本文复制引用

孙铜,伍碧,彭蜀君,孙维义,丁桑岚,苏仕军..从废旧碱性锌锰电池极性材料中浸出锌的试验研究[J].湿法冶金,2013,(4):252-255,4.

基金项目

新世纪优秀人才支持计划项目(NCET-09-0570);四川省杰出青年基金项目(2011JQ0008);四川省博士后基金资助项目。 ()

湿法冶金

OA北大核心

1009-2617

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