物理化学学报Issue(4)：701-705,5.DOI:10.3866/PKU.WHXB201302212
[Fe（N2H5）2（SO4）2]n的合成、结构和磁性质
Synthesis, Structure and Magnetic Properties of Iron(II) Sulfate Containing Hydrazine
摘要
Abstract
A novel transition metal iron(II) sulfate containing hydrazine (N2H4), [Fe(N2H5)2(SO4)2]n (1), is prepared by a hydrothermal method. Single-crystal X-ray diffraction reveals that 1 consists of one-dimensional (1D) sulfate-bridged homometal ic chains with protonated hydrazine molecules as terminal ligands. Hydrogen bonds between protonated hydrazine and sulfate ions connect the chains into a three-dimensional (3D) extended framework. Magnetic measurements indicate that 1 exhibits the antiferromagnetic ordering behavior at low temperature.关键词
肼/硫酸根/亚铁离子/反铁磁交换作用/磁有序Key words
Hydrazine/Sulfate group/Ferrous ion/Antiferromagnetic interaction/Magnetic ordering分类
化学化工引用本文复制引用
王艳君,贾丽慧,王炳武..[Fe（N2H5）2（SO4）2]n的合成、结构和磁性质[J].物理化学学报,2013,(4):701-705,5.基金项目
The project was supported by the National Natural Science Foundation of China (21101123,21071008).国家自然科学基金(21101123,21071008)资助项目 （21101123,21071008）
