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水体重金属激光诱导击穿光谱定量分析方法对比研究*

王春龙 章炜 刘晶 张玉钧 刘文清 刘建国 赵南京 马明俊 王寅 胡丽 张大海 余洋 孟德硕

物理学报Issue(12):1-6,6.
物理学报Issue(12):1-6,6.DOI:10.7498/aps.62.125201

水体重金属激光诱导击穿光谱定量分析方法对比研究*

Comparative analysis of quantitative method on heavy metal detection in water with laser-induced breakdown spectroscopy∗

王春龙 1章炜 1刘晶 1张玉钧 1刘文清 1刘建国 1赵南京 1马明俊 1王寅 1胡丽 1张大海 1余洋 1孟德硕1

作者信息

  • 1. 中国科学院安徽光学精密机械研究所,中国科学院环境光学与技术重点实验室,合肥 230031
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摘要

Abstract

  The quantitative analysis models of multiple linear regression, neural network regression and support vector machine regression with laser-induced breakdown spectroscopy are established in this paper. Heavy metal Ni in water selected as research object is tested and comparativly analyzed. The average relative standard deviations of multiple linear regression, neural network regression and support vector machine regression are 7.60%, 4.86%and 2.35%, and the maximum standard deviations are 23.35%, 15.20%and 8.29%respectively, the average relative errors are 25.98%, 10.58%and 2.72%, and the maximum relative errors are 116.47%, 47.38%and 9.89%respectively. Methods and reference data are provided for the further study of fast measurement of tracing heavy metals in water by laser induced breakdown spectroscopy technique.

关键词

光谱学/激光诱导击穿光谱/支持向量机回归/重金属

Key words

spectroscopy/laser-induced breakdown spectroscopy/support vector machine regression/heavy metals

引用本文复制引用

王春龙,章炜,刘晶,张玉钧,刘文清,刘建国,赵南京,马明俊,王寅,胡丽,张大海,余洋,孟德硕..水体重金属激光诱导击穿光谱定量分析方法对比研究*[J].物理学报,2013,(12):1-6,6.

基金项目

国家自然科学基金(批准号:60908018)和国家重大科技专项(批准号:2009ZX07527-007,2009ZX07420-008,2011ZX05051)资助的课题 (批准号:60908018)

物理学报

OA北大核心CSCDCSTPCD

1000-3290

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