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碳纳米管掺杂对聚合物聚(2-甲氧基-5-辛氧基)对苯乙炔-PbSe量子点复合材料性能的影响*

屈俊荣 郑建邦 王春锋 吴广荣 王雪艳

物理学报Issue(12):1-7,7.
物理学报Issue(12):1-7,7.DOI:10.7498/aps.62.128801

碳纳米管掺杂对聚合物聚(2-甲氧基-5-辛氧基)对苯乙炔-PbSe量子点复合材料性能的影响*

Effect of carbon nanotubes on the properties of polymer MOPPV-PbSe quantum dot composites∗

屈俊荣 1郑建邦 1王春锋 1吴广荣 1王雪艳1

作者信息

  • 1. 西北工业大学应用物理系,陕西省光信息技术重点实验室,西安 710072
  • 折叠

摘要

Abstract

  According to single-walled carbon nanotube good conductivity, baryon transmission performance, and high photoelectric con-version performance of quantum dot composite material, in this letter, we use in situ condensation method to prepare polymer/poly (2-methoxy, 5-oc-toxy)-1, 4-phenylenevinylene (MOPPV)-single walled carbon nanotubes/PbSe quantum dot composites and use X-ray diffraction, transmission electron microscope, UV-vis absorption spectroscopy to study their characteristics. The results indicate that MOPPV, SWNT and PbSe quantum dots can be effectively combined, especially the SWNT and MOPPV form a network struc-ture in MOPPV matrix, and PbSe quantum dots, each with an average size of 5.75 nm, can be dispersed to form a coating or mosaic structure in the polymer substrate of MOPPV-SWNT, producing the light induced charge transfer phenomenon. The study of compos-ite photoelectric performance shows that when the polymer MOPPV, SWNT, PbSe have their mass ratio of 1:0.3:1, the composite photoelectric performance is best: open circuit voltage is 0.556 V, short circuit current is 2.133 mA, fill factor is 34.48%, conversion efficiency is 0.452%. Compared with the polymer MOPPV-PbSe quantum dots composite materials, the optoelectronic properties are increased by 2–3 times.

关键词

量子点/碳纳米管/复合材料/转换效率

Key words

quantum dot/carbon nanotubes/composite materials/power conversion effiency

引用本文复制引用

屈俊荣,郑建邦,王春锋,吴广荣,王雪艳..碳纳米管掺杂对聚合物聚(2-甲氧基-5-辛氧基)对苯乙炔-PbSe量子点复合材料性能的影响*[J].物理学报,2013,(12):1-7,7.

基金项目

西北工业大学博士论文创新基金(批准号:CX201324)资助的课题 (批准号:CX201324)

物理学报

OA北大核心CSCDCSTPCD

1000-3290

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